Sulfonated styrene−divinybenzene resins / Muhammad Arif Malik in Industrial & engineering chemistry research, Vol. 49 N° 6 (Mars 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 6 (Mars 2010) . - pp. 2608–2612 Titre : Sulfonated styrene−divinybenzene resins : optimizing synthesis and estimating characteristics of the base copolymers and the resins Type de document : texte imprimé Auteurs : Muhammad Arif Malik, Auteur ; Syed Wasim Ali, Auteur ; Imtiaz Ahmed, Auteur Année de publication : 2010 Article en page(s) : pp. 2608–2612 Note générale : Industrial Chemistry Langues : Anglais (eng) Mots-clés : Sulfonated Styrene Divinybenzene Resins Optimizing Synthesis Characteristics Base Copolymers Résumé : Maximum sulfonation and minimum carboxylation are desirable in sulfonated styrene−divinylbenzene cation-exchange resins. These characteristics may be achieved with greater control of porosity of the base copolymers. Optimization of the porosity by varying both the nature and amount of porogen, and cross-linking for maximizing sulfonation and minimizing carboxylation, are reported. Predictors of the characteristics obtained by statistical analysis of the data, and the ranges of conditions in which they can be employed, are discussed. The optimum conditions are cross-linking 20% to 23% and pore volume 0.14 mL/g to 0.3 mL/g. The relationship of the particle size with porosity of the base copolymer and capacity of the resins is discussed. The effects of residual porogen/homopolymer on the sulfonation of these copolymers are also discussed. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie902057x [article] Sulfonated styrene−divinybenzene resins : optimizing synthesis and estimating characteristics of the base copolymers and the resins [texte imprimé] / Muhammad Arif Malik, Auteur ; Syed Wasim Ali, Auteur ; Imtiaz Ahmed, Auteur . - 2010 . - pp. 2608–2612. Industrial Chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 6 (Mars 2010) . - pp. 2608–2612 Mots-clés : Sulfonated Styrene Divinybenzene Resins Optimizing Synthesis Characteristics Base Copolymers Résumé : Maximum sulfonation and minimum carboxylation are desirable in sulfonated styrene−divinylbenzene cation-exchange resins. These characteristics may be achieved with greater control of porosity of the base copolymers. Optimization of the porosity by varying both the nature and amount of porogen, and cross-linking for maximizing sulfonation and minimizing carboxylation, are reported. Predictors of the characteristics obtained by statistical analysis of the data, and the ranges of conditions in which they can be employed, are discussed. The optimum conditions are cross-linking 20% to 23% and pore volume 0.14 mL/g to 0.3 mL/g. The relationship of the particle size with porosity of the base copolymer and capacity of the resins is discussed. The effects of residual porogen/homopolymer on the sulfonation of these copolymers are also discussed. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie902057x

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