Conversion of benzylic bromides to benzaldehydes using sodium nitrate as an oxidant / K. Kulangiappar in Industrial & engineering chemistry research, Vol. 49 N° 14 (Juillet 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 14 (Juillet 2010) . - pp. 6670–6673 Titre : Conversion of benzylic bromides to benzaldehydes using sodium nitrate as an oxidant Type de document : texte imprimé Auteurs : K. Kulangiappar, Auteur ; M. Anbu Kulandainathan, Auteur ; T. Raju, Auteur Année de publication : 2010 Article en page(s) : pp. 6670–6673 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Sodium nitrate Oxidant Résumé : A simple and effective approach for the synthesis of benzaldehydes from benzylic bromides is reported using sodium nitrate as an oxidant with 10% sodium hydroxide. Benzyl bromide is oxidized to benzaldehyde in 91% yield with 98% conversion at 120 °C, whereas 82% of benzyl alcohol is obtained at a temperature of 80 °C in 80 min with 20% sodium nitrate solution. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901986g [article] Conversion of benzylic bromides to benzaldehydes using sodium nitrate as an oxidant [texte imprimé] / K. Kulangiappar, Auteur ; M. Anbu Kulandainathan, Auteur ; T. Raju, Auteur . - 2010 . - pp. 6670–6673. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 14 (Juillet 2010) . - pp. 6670–6673 Mots-clés : Sodium nitrate Oxidant Résumé : A simple and effective approach for the synthesis of benzaldehydes from benzylic bromides is reported using sodium nitrate as an oxidant with 10% sodium hydroxide. Benzyl bromide is oxidized to benzaldehyde in 91% yield with 98% conversion at 120 °C, whereas 82% of benzyl alcohol is obtained at a temperature of 80 °C in 80 min with 20% sodium nitrate solution. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901986g

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