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Flow induced unstable structure of liquid crystalline polymer solution in L-shaped slit channels / Takatsune Narumi in Transactions of the ASME . Journal of fluids engineering, Vol. 130 N° 8 (Août 2008) 

Public ISBD [article]  in Transactions of the ASME . Journal of fluids engineering > Vol. 130 N° 8 (Août 2008) . - 6 p. Titre : Flow induced unstable structure of liquid crystalline polymer solution in L-shaped slit channels Type de document : texte imprimé Auteurs : Takatsune Narumi, Auteur ; Jun Fukada, Auteur ; Satoru Kiryu, Auteur Année de publication : 2009 Article en page(s) : 6 p. Note générale : Fluids engineering Langues : Anglais (eng) Mots-clés : Flow  (dynamics);  channels  (hydraulic  engineering);  corners  (structural  elements);  liquid  crystalline  polymers;  texture  (materials) Résumé : An experimental study has been conducted on unstable structures induced in two-dimensional slit flows of liquid crystalline polymer solution. 50wt% aqueous solution of hydroxyl-propylcellulose (HPC) was utilized as a test fluid and its flow behavior in L-shaped slit channels with a cross section of 1mm height and 16mm width was measured optically. The inner corner of the L-shaped channel was rounded off in order to clarify the influence of the radius of curvature on the unstable behavior. A conversing curved channel was also tested. The flow patterns of the HPC solution in the channels were visualized with two crossed polarizers and we observed that typical wavy textures generated in the upstream of the corner almost disappeared after the corner flow. However, an unstable texture was developed again only from the inner corner in downstream flow. The fluctuation of the orientation angle and dichroism were also measured with a laser opto-rheometric system and it was found that the unstable behaviors of the HPC solution have periodic oscillatory characteristics at a typical frequency. In the inner side flow after the corner, the periodic motion became larger toward the downstream and then higher harmonic oscillations were superimposed. Larger rounding off of the inner corner suppressed the redevelopment of unstable behavior, and it is considered that the rapid regrowth of unstable behavior was caused by rapid deceleration at the corner flow. Moreover, the unstable structure was stabilized with an accelerated (elongated) region in the corner flow and the converging channel was helpful to obtain a stable structure in the downstream region. En ligne : http://fluidsengineering.asmedigitalcollection.asme.org/article.aspx?articleID=1 [...] [article] Flow induced unstable structure of liquid crystalline polymer solution in L-shaped slit channels [texte imprimé] / Takatsune Narumi, Auteur ; Jun Fukada, Auteur ; Satoru Kiryu, Auteur . - 2009 . - 6 p. Fluids engineering Langues : Anglais (eng) in Transactions of the ASME . Journal of fluids engineering > Vol. 130 N° 8 (Août 2008) . - 6 p. Mots-clés : Flow  (dynamics);  channels  (hydraulic  engineering);  corners  (structural  elements);  liquid  crystalline  polymers;  texture  (materials) Résumé : An experimental study has been conducted on unstable structures induced in two-dimensional slit flows of liquid crystalline polymer solution. 50wt% aqueous solution of hydroxyl-propylcellulose (HPC) was utilized as a test fluid and its flow behavior in L-shaped slit channels with a cross section of 1mm height and 16mm width was measured optically. The inner corner of the L-shaped channel was rounded off in order to clarify the influence of the radius of curvature on the unstable behavior. A conversing curved channel was also tested. The flow patterns of the HPC solution in the channels were visualized with two crossed polarizers and we observed that typical wavy textures generated in the upstream of the corner almost disappeared after the corner flow. However, an unstable texture was developed again only from the inner corner in downstream flow. The fluctuation of the orientation angle and dichroism were also measured with a laser opto-rheometric system and it was found that the unstable behaviors of the HPC solution have periodic oscillatory characteristics at a typical frequency. In the inner side flow after the corner, the periodic motion became larger toward the downstream and then higher harmonic oscillations were superimposed. Larger rounding off of the inner corner suppressed the redevelopment of unstable behavior, and it is considered that the rapid regrowth of unstable behavior was caused by rapid deceleration at the corner flow. Moreover, the unstable structure was stabilized with an accelerated (elongated) region in the corner flow and the converging channel was helpful to obtain a stable structure in the downstream region. En ligne : http://fluidsengineering.asmedigitalcollection.asme.org/article.aspx?articleID=1 [...]

Modeling and measurement of the dynamic surface tension of surfactant solutions / Tomiichi Hasegawa in Transactions of the ASME . Journal of fluids engineering, Vol. 130 N° 8 (Août 2008) 

Public ISBD [article]  in Transactions of the ASME . Journal of fluids engineering > Vol. 130 N° 8 (Août 2008) . - 8 p. Titre : Modeling and measurement of the dynamic surface tension of surfactant solutions Type de document : texte imprimé Auteurs : Tomiichi Hasegawa, Auteur ; Masahiro Karasawa, Auteur ; Takatsune Narumi, Auteur Année de publication : 2009 Article en page(s) : 8 p. Note générale : Fluids engineering Langues : Anglais (eng) Mots-clés : Surface  tension;  equilibrium  (physics);  surfactants;  water;  modeling Résumé : Surfactant solutions are usually used under conditions accompanied by transient dynamic surfaces, and therefore the dynamic surface tension (DST) is important in many industrial processes. Theories regarding DST have been developed exclusively on the adsorption theory that molecules are transported from bulk solution to the interface. However, the adsorption theory is not closed and requires another relationship between the interfacial concentration of the adsorbing molecules and the bulk concentration of molecules near and at the surface, which at present is based on assumptions. In addition, DST obtained by the adsorption theory contains several parameters that must be determined beforehand, and it is not simple to use for practical purposes. Here, we propose a new model based on the concept that surfactant molecules rotate during the process reaching the equilibrium surface state, which is different from the conventional adsorption theory, and we obtained a simple expression of DST as a function of the surface age. In addition, an experiment was carried out to determine DST by measuring the period and weight of droplets falling from a capillary. The expression by the proposed model was compared with the results of this experiment and with those reported previously by several other authors, and good agreement was obtained. Furthermore, the characteristic time in the model was shown to be correlated with the concentrations of solutions regardless of the type of solutions examined. En ligne : http://fluidsengineering.asmedigitalcollection.asme.org/Issue.aspx?issueID=27329 [...] [article] Modeling and measurement of the dynamic surface tension of surfactant solutions [texte imprimé] / Tomiichi Hasegawa, Auteur ; Masahiro Karasawa, Auteur ; Takatsune Narumi, Auteur . - 2009 . - 8 p. Fluids engineering Langues : Anglais (eng) in Transactions of the ASME . Journal of fluids engineering > Vol. 130 N° 8 (Août 2008) . - 8 p. Mots-clés : Surface  tension;  equilibrium  (physics);  surfactants;  water;  modeling Résumé : Surfactant solutions are usually used under conditions accompanied by transient dynamic surfaces, and therefore the dynamic surface tension (DST) is important in many industrial processes. Theories regarding DST have been developed exclusively on the adsorption theory that molecules are transported from bulk solution to the interface. However, the adsorption theory is not closed and requires another relationship between the interfacial concentration of the adsorbing molecules and the bulk concentration of molecules near and at the surface, which at present is based on assumptions. In addition, DST obtained by the adsorption theory contains several parameters that must be determined beforehand, and it is not simple to use for practical purposes. Here, we propose a new model based on the concept that surfactant molecules rotate during the process reaching the equilibrium surface state, which is different from the conventional adsorption theory, and we obtained a simple expression of DST as a function of the surface age. In addition, an experiment was carried out to determine DST by measuring the period and weight of droplets falling from a capillary. The expression by the proposed model was compared with the results of this experiment and with those reported previously by several other authors, and good agreement was obtained. Furthermore, the characteristic time in the model was shown to be correlated with the concentrations of solutions regardless of the type of solutions examined. En ligne : http://fluidsengineering.asmedigitalcollection.asme.org/Issue.aspx?issueID=27329 [...]