Article : texte imprimé

Osmium(VIII) catalyzed oxidative cleavage of pyrrolidine ring in l-proline by hexacyanoferrate(III) in alkaline media

K. Sharanabasamma, Auteur ; Mahantesh A. Angadi, Auteur ; Manjalee S. Salunke, Auteur |

Dans Industrial & engineering chemistry research (Vol. 48 N° 23, Décembre 2009)

Kinetics of oxidation of l-proline by hexacyanoferrate(III) catalyzed by osmium(VIII) in alkaline medium was studied at 30 °C. A mechanism involving free radical path was proposed. Rate law of the reaction was derived as The rate constant k a[...]

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