[article]
Titre : |
Au/FeOx−TiO2 catalysts for the preferential oxidation of CO in a H2 stream |
Type de document : |
texte imprimé |
Auteurs : |
Yi-Fen Yang, Auteur ; Palanivelu Sangeetha, Auteur ; Chen, Yu-Wen, Auteur |
Année de publication : |
2010 |
Article en page(s) : |
pp. 10402–10407 |
Note générale : |
Industrial chemistry |
Langues : |
Anglais (eng) |
Mots-clés : |
Au/FeOx− TiO2--Catalysts--Preferential--Oxidation--CO--H2--Stream |
Résumé : |
A series of gold catalysts supported on Fe2O3−TiO2 with various iron contents were prepared. A FeOx−TiO2 support was prepared via incipient-wetness impregnation with aqueous solution of Fe(NO3)3 on TiO2. A gold catalyst with a nominal loading of 1 wt % was prepared by deposition−precipitation at pH 7 and 65 °C. The catalysts were characterized by X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. The catalytic performance of these catalysts were investigated by preferential oxidation of carbon monoxide in hydrogen stream (PROX). The reaction was conducted in a fixed-bed microreactor with a feed of CO:O2:H2:He = 1:1:49:49 (volume ratios). A limited amount of oxygen was used. Gold catalysts have been reported to be efficient catalysts for the PROX reaction to reduce CO concentration to |
ISSN : |
0888-5885 |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie900806r |
in Industrial & engineering chemistry research > Vol. 48 N° 23 (Décembre 2009) . - pp. 10402–10407
[article] Au/FeOx−TiO2 catalysts for the preferential oxidation of CO in a H2 stream [texte imprimé] / Yi-Fen Yang, Auteur ; Palanivelu Sangeetha, Auteur ; Chen, Yu-Wen, Auteur . - 2010 . - pp. 10402–10407. Industrial chemistry Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 48 N° 23 (Décembre 2009) . - pp. 10402–10407
Mots-clés : |
Au/FeOx− TiO2--Catalysts--Preferential--Oxidation--CO--H2--Stream |
Résumé : |
A series of gold catalysts supported on Fe2O3−TiO2 with various iron contents were prepared. A FeOx−TiO2 support was prepared via incipient-wetness impregnation with aqueous solution of Fe(NO3)3 on TiO2. A gold catalyst with a nominal loading of 1 wt % was prepared by deposition−precipitation at pH 7 and 65 °C. The catalysts were characterized by X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. The catalytic performance of these catalysts were investigated by preferential oxidation of carbon monoxide in hydrogen stream (PROX). The reaction was conducted in a fixed-bed microreactor with a feed of CO:O2:H2:He = 1:1:49:49 (volume ratios). A limited amount of oxygen was used. Gold catalysts have been reported to be efficient catalysts for the PROX reaction to reduce CO concentration to |
ISSN : |
0888-5885 |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie900806r |
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