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The Modified Sanchez−Lacombe Equation of State Applied to Polydisperse Polyethylene Solutions / Ryan A. Krenz in Industrial & engineering chemistry research, Vol. 48 N° 23 (Décembre 2009) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 48 N° 23 (Décembre 2009) . - pp. 10664–10681 Titre : The Modified Sanchez−Lacombe Equation of State Applied to Polydisperse Polyethylene Solutions Type de document : texte imprimé Auteurs : Ryan A. Krenz, Auteur ; Torben Laursen, Auteur ; Robert A. Heidemann, Auteur Année de publication : 2010 Article en page(s) : pp. 10664–10681 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Modified--Sanchez−Lacombe--Equation--Applied--Polydisperse--Polyethylene--Solutions Résumé : The modified Sanchez−Lacombe equation of state (MSL-EOS) is Neau’s version of the Sanchez−Lacombe equation of state modified to include a Péneloux-type volume translation. The purpose of this work is to report parameters for modeling the phase behavior of polyethylene solutions. The MSL equation is an empirical equation that contains four parameters to define each pure compound whether a solvent or a polydisperse polymer. The MSL equation uses conventional linear and quadratic mixing rules. A parametrization can be used to obtain the pure compound parameters from the molar mass, critical temperature, critical pressure, and acentric factor. These properties cannot be defined for polydisperse polymers, and parameters were determined from a combination of liquid density (PVT) data and polymer + solvent cloud point (xPT) data. Binary interaction parameters have been obtained for over 50 mixtures by correlating the fluid phase boundaries. Binary mixtures including ethylene, hexane, and/or cyclohexane are of particular interest to polyethylene production. A single binary interaction parameter is usually sufficient to represent vapor−liquid equilibrium, but temperature dependence is required to accurately represent liquid−liquid equilibrium. The MSL equation of state can be used to correlate the cloud points of polyethylene solutions at high pressures. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie801451a [article] The Modified Sanchez−Lacombe Equation of State Applied to Polydisperse Polyethylene Solutions [texte imprimé] / Ryan A. Krenz, Auteur ; Torben Laursen, Auteur ; Robert A. Heidemann, Auteur . - 2010 . - pp. 10664–10681. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N° 23 (Décembre 2009) . - pp. 10664–10681 Mots-clés : Modified--Sanchez−Lacombe--Equation--Applied--Polydisperse--Polyethylene--Solutions Résumé : The modified Sanchez−Lacombe equation of state (MSL-EOS) is Neau’s version of the Sanchez−Lacombe equation of state modified to include a Péneloux-type volume translation. The purpose of this work is to report parameters for modeling the phase behavior of polyethylene solutions. The MSL equation is an empirical equation that contains four parameters to define each pure compound whether a solvent or a polydisperse polymer. The MSL equation uses conventional linear and quadratic mixing rules. A parametrization can be used to obtain the pure compound parameters from the molar mass, critical temperature, critical pressure, and acentric factor. These properties cannot be defined for polydisperse polymers, and parameters were determined from a combination of liquid density (PVT) data and polymer + solvent cloud point (xPT) data. Binary interaction parameters have been obtained for over 50 mixtures by correlating the fluid phase boundaries. Binary mixtures including ethylene, hexane, and/or cyclohexane are of particular interest to polyethylene production. A single binary interaction parameter is usually sufficient to represent vapor−liquid equilibrium, but temperature dependence is required to accurately represent liquid−liquid equilibrium. The MSL equation of state can be used to correlate the cloud points of polyethylene solutions at high pressures. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie801451a