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Intrinsic kinetics of catalytic hydrogenation of cardanol / Zhi-Bo Mao in Industrial & engineering chemistry research, Vol. 48 N° 22 (Novembre 2009) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 48 N° 22 (Novembre 2009) . - pp. 9910–9914 Titre : Intrinsic kinetics of catalytic hydrogenation of cardanol Type de document : texte imprimé Auteurs : Zhi-Bo Mao, Auteur ; Ting-Liang Luo, Auteur ; Hong-Tao Cheng, Auteur Année de publication : 2010 Article en page(s) : pp. 9910–9914 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Cardanol  Catalytic  hydrogenation  Raney  nickel  catalyst Résumé : The experiment of catalytic hydrogenation of cardanol was performed on a Raney nickel catalyst for the purpose of eliminating the effects of internal and external diffusion. The kinetics data have been collected experimentally over ranges of 2.5−4 MPa and 373.15−393.15 K, respectively. Then, the intrinsic kinetics of the catalytic hydrogenation reaction of cardanol was studied. It was proven that the catalytic hydrogenation of cardanol is a second-order irreversible series-parallel reaction under the experimental conditions. The kinetic parameters (Ea, K0) and kinetic equation were obtained through fitting, and the kinetic model was proven through testing to be reliable. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900655a [article] Intrinsic kinetics of catalytic hydrogenation of cardanol [texte imprimé] / Zhi-Bo Mao, Auteur ; Ting-Liang Luo, Auteur ; Hong-Tao Cheng, Auteur . - 2010 . - pp. 9910–9914. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N° 22 (Novembre 2009) . - pp. 9910–9914 Mots-clés : Cardanol  Catalytic  hydrogenation  Raney  nickel  catalyst Résumé : The experiment of catalytic hydrogenation of cardanol was performed on a Raney nickel catalyst for the purpose of eliminating the effects of internal and external diffusion. The kinetics data have been collected experimentally over ranges of 2.5−4 MPa and 373.15−393.15 K, respectively. Then, the intrinsic kinetics of the catalytic hydrogenation reaction of cardanol was studied. It was proven that the catalytic hydrogenation of cardanol is a second-order irreversible series-parallel reaction under the experimental conditions. The kinetic parameters (Ea, K0) and kinetic equation were obtained through fitting, and the kinetic model was proven through testing to be reliable. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900655a