Linear free energy relationship correlations for enthalpies of solvation of organic solutes into room-temperature ionic liquids based on the abraham model with ion-specific equation coefficients / Laura M. Sprunger in Industrial & engineering chemistry research, Vol. 48 N° 18 (Septembre 2009)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 48 N° 18 (Septembre 2009) . - pp. 8704–8709 Titre : Linear free energy relationship correlations for enthalpies of solvation of organic solutes into room-temperature ionic liquids based on the abraham model with ion-specific equation coefficients Type de document : texte imprimé Auteurs : Laura M. Sprunger, Auteur ; Sai S. Achi, Auteur ; William E. Acree Jr., Auteur Année de publication : 2010 Article en page(s) : pp. 8704–8709 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Mathematical correlations Organic solutesRoom-temperature ionic liquids Abraham general solvation model Résumé : Mathematical correlations have been developed for describing the enthalpy of solvation of organic solutes into room-temperature ionic liquids (RTILs) based on the Abraham general solvation model with ion-specific equation coefficients. The derived correlations contain six cation-specific and six anion-specific equation coefficients that were determined through regression analyses. The derived equations correlated the observed enthalpies of solvation data to within a standard deviation of about 1.7 kJ/mol. The nine sets of cation-specific and eight sets of anion-specific equation coefficients that have been calculated can be combined to yield equations capable of predicting the enthalpies of solvation of organic solutes and gases in 72 different RTILs. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900788p [article] Linear free energy relationship correlations for enthalpies of solvation of organic solutes into room-temperature ionic liquids based on the abraham model with ion-specific equation coefficients [texte imprimé] / Laura M. Sprunger, Auteur ; Sai S. Achi, Auteur ; William E. Acree Jr., Auteur . - 2010 . - pp. 8704–8709. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N° 18 (Septembre 2009) . - pp. 8704–8709 Mots-clés : Mathematical correlations Organic solutesRoom-temperature ionic liquids Abraham general solvation model Résumé : Mathematical correlations have been developed for describing the enthalpy of solvation of organic solutes into room-temperature ionic liquids (RTILs) based on the Abraham general solvation model with ion-specific equation coefficients. The derived correlations contain six cation-specific and six anion-specific equation coefficients that were determined through regression analyses. The derived equations correlated the observed enthalpies of solvation data to within a standard deviation of about 1.7 kJ/mol. The nine sets of cation-specific and eight sets of anion-specific equation coefficients that have been calculated can be combined to yield equations capable of predicting the enthalpies of solvation of organic solutes and gases in 72 different RTILs. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900788p

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Linear free energy relationship correlations for enthalpies of solvation of organic solutes into room-temperature ionic liquids based on the abraham model with ion-specific equation coefficients / Laura M. Sprunger in Industrial & engineering chemistry research, Vol. 48 N° 18 (Septembre 2009)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 48 N° 18 (Septembre 2009) . - pp. 8704–8709 Titre : Linear free energy relationship correlations for enthalpies of solvation of organic solutes into room-temperature ionic liquids based on the abraham model with ion-specific equation coefficients Type de document : texte imprimé Auteurs : Laura M. Sprunger, Auteur ; Sai S. Achi, Auteur ; William E. Acree Jr., Auteur Année de publication : 2010 Article en page(s) : pp. 8704–8709 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Mathematical correlations Organic solutesRoom-temperature ionic liquids Abraham general solvation model Résumé : Mathematical correlations have been developed for describing the enthalpy of solvation of organic solutes into room-temperature ionic liquids (RTILs) based on the Abraham general solvation model with ion-specific equation coefficients. The derived correlations contain six cation-specific and six anion-specific equation coefficients that were determined through regression analyses. The derived equations correlated the observed enthalpies of solvation data to within a standard deviation of about 1.7 kJ/mol. The nine sets of cation-specific and eight sets of anion-specific equation coefficients that have been calculated can be combined to yield equations capable of predicting the enthalpies of solvation of organic solutes and gases in 72 different RTILs. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900788p [article] Linear free energy relationship correlations for enthalpies of solvation of organic solutes into room-temperature ionic liquids based on the abraham model with ion-specific equation coefficients [texte imprimé] / Laura M. Sprunger, Auteur ; Sai S. Achi, Auteur ; William E. Acree Jr., Auteur . - 2010 . - pp. 8704–8709. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N° 18 (Septembre 2009) . - pp. 8704–8709 Mots-clés : Mathematical correlations Organic solutesRoom-temperature ionic liquids Abraham general solvation model Résumé : Mathematical correlations have been developed for describing the enthalpy of solvation of organic solutes into room-temperature ionic liquids (RTILs) based on the Abraham general solvation model with ion-specific equation coefficients. The derived correlations contain six cation-specific and six anion-specific equation coefficients that were determined through regression analyses. The derived equations correlated the observed enthalpies of solvation data to within a standard deviation of about 1.7 kJ/mol. The nine sets of cation-specific and eight sets of anion-specific equation coefficients that have been calculated can be combined to yield equations capable of predicting the enthalpies of solvation of organic solutes and gases in 72 different RTILs. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900788p

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