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Synthesis, structure, and photocatalytic activity in orthorhombic perovskites LnVO3 and Ln1−xTixVO3 (Ln = Ce, Pr, and Nd) / Dipankar Saha in Industrial & engineering chemistry research, Vol. 48 N° 16 (Août 2009) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 48 N° 16 (Août 2009) . - pp. 7489–7497 Titre : Synthesis, structure, and photocatalytic activity in orthorhombic perovskites LnVO3 and Ln1−xTixVO3 (Ln = Ce, Pr, and Nd) Type de document : texte imprimé Auteurs : Dipankar Saha, Auteur ; Sudarshan Mahapatra, Auteur ; T. N. Guru Row, Auteur Année de publication : 2009 Article en page(s) : pp. 7489–7497 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : LnVO3  Ln1−xTixVO3  (Ln  =  Ce,  Pr,  and  Nd)  Solid  state  method  Fourier  analysis Résumé : Orthorhombic perovskite type LnVO3 and Ln1−xTixVO3 (Ln = Ce, Pr, and Nd) have been synthesized by the solid state method. The structures of these compounds have been unequivocally established based on high resolution powder X-ray diffraction data using Rietveld refinement methodology followed by difference Fourier analysis. It is shown that substitution of Ti occurs at the vanadium site and not at the cerium site. The compounds have been tested for photocatalytic degradation of various dyes and substituted phenols. It is observed that doping of Ti remarkably improves the photodegradation efficiency of these orthorhombic perovskites. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie9006134 [article] Synthesis, structure, and photocatalytic activity in orthorhombic perovskites LnVO3 and Ln1−xTixVO3 (Ln = Ce, Pr, and Nd) [texte imprimé] / Dipankar Saha, Auteur ; Sudarshan Mahapatra, Auteur ; T. N. Guru Row, Auteur . - 2009 . - pp. 7489–7497. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N° 16 (Août 2009) . - pp. 7489–7497 Mots-clés : LnVO3  Ln1−xTixVO3  (Ln  =  Ce,  Pr,  and  Nd)  Solid  state  method  Fourier  analysis Résumé : Orthorhombic perovskite type LnVO3 and Ln1−xTixVO3 (Ln = Ce, Pr, and Nd) have been synthesized by the solid state method. The structures of these compounds have been unequivocally established based on high resolution powder X-ray diffraction data using Rietveld refinement methodology followed by difference Fourier analysis. It is shown that substitution of Ti occurs at the vanadium site and not at the cerium site. The compounds have been tested for photocatalytic degradation of various dyes and substituted phenols. It is observed that doping of Ti remarkably improves the photodegradation efficiency of these orthorhombic perovskites. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie9006134