Synthesis of a water-soluble siloxane copolymer and its application for antimicrobial coatings / L. Kou in Industrial & engineering chemistry research, Vol. 48 N° 14 (Juillet 2009)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 48 N° 14 (Juillet 2009) . - pp. 6521–6526 Titre : Synthesis of a water-soluble siloxane copolymer and its application for antimicrobial coatings Type de document : texte imprimé Auteurs : L. Kou, Auteur ; J. Liang, Auteur ; X. Ren, Auteur Année de publication : 2009 Article en page(s) : pp. 6521–6526 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : N-halamine siloxane Quaternary ammonium salt Copolymers 5,5-dimethylhydantoin Trimethylamine Résumé : Copolymers of an N-halamine siloxane and a quaternary ammonium salt siloxane were prepared using 5,5-dimethylhydantoin and trimethylamine as functional groups. The solubility of this siloxane copolymer in water was dramatically improved over that of a hydantoinyl siloxane homopolymer developed earlier. The biocidal activity of cotton swatches coated with the copolymer was evaluated against S. aureus and E. coli O157:H7; the antimicrobial fabric with 0.23%−0.26% chlorine loading could inactivate 107 colony forming units (CFU) of bacteria within 1−5 min of contact. It was observed that a 1 wt % coating bath could provide a coating that could be chlorinated to greater than a 0.20% chlorine loading for a copolymer having a 9:1 ratio of hydantoin to quat moieties. The stability of the oxidative chlorine loading on the cotton swatches was not affected by the presence of the very hydrophilic quat functional group. Use of the copolymer in an antimicrobial coating application will be desirable because no organic solvent is needed for the preparation of a coating bath for textile materials. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8017302 [article] Synthesis of a water-soluble siloxane copolymer and its application for antimicrobial coatings [texte imprimé] / L. Kou, Auteur ; J. Liang, Auteur ; X. Ren, Auteur . - 2009 . - pp. 6521–6526. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N° 14 (Juillet 2009) . - pp. 6521–6526 Mots-clés : N-halamine siloxane Quaternary ammonium salt Copolymers 5,5-dimethylhydantoin Trimethylamine Résumé : Copolymers of an N-halamine siloxane and a quaternary ammonium salt siloxane were prepared using 5,5-dimethylhydantoin and trimethylamine as functional groups. The solubility of this siloxane copolymer in water was dramatically improved over that of a hydantoinyl siloxane homopolymer developed earlier. The biocidal activity of cotton swatches coated with the copolymer was evaluated against S. aureus and E. coli O157:H7; the antimicrobial fabric with 0.23%−0.26% chlorine loading could inactivate 107 colony forming units (CFU) of bacteria within 1−5 min of contact. It was observed that a 1 wt % coating bath could provide a coating that could be chlorinated to greater than a 0.20% chlorine loading for a copolymer having a 9:1 ratio of hydantoin to quat moieties. The stability of the oxidative chlorine loading on the cotton swatches was not affected by the presence of the very hydrophilic quat functional group. Use of the copolymer in an antimicrobial coating application will be desirable because no organic solvent is needed for the preparation of a coating bath for textile materials. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8017302

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