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Toward the Efficient production of methane/propane double hydrate / Melissa R. Prado in Industrial & engineering chemistry research, Vol. 48 N° 11 (Juin 2009) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 48 N° 11 (Juin 2009) . - pp. 5160–5164 Titre : Toward the Efficient production of methane/propane double hydrate Type de document : texte imprimé Auteurs : Melissa R. Prado, Auteur ; Yazmin Cazares, Auteur ; Kenneth C. Janda, Auteur Année de publication : 2009 Article en page(s) : pp. 5160–5164 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Propane  hydrate  Methane  gas  Methane/propane  gas  mixture Résumé : Propane hydrate has been studied to investigate its use as a possible storage medium for methane gas. For practical purposes, hydrate formation needs to be efficient at near ambient conditions. Ice particles exposed to varying mixtures of propane and methane gas are found to form the double hydrate efficiently and may be quite effective for storing methane. For instance, exposure of the ice particles to a 2/1 methane/propane gas mixture for 18 h converts 66% of the ice to hydrate with 77% occupancy of the 512 cages and a final dissociation temperature of 287 K. The samples were then decomposed to determine the pressure versus temperature at a rate of 1 K/h. It was found that deviations from equilibrium were minor. The compositions of the hydrates were determined via gas chromatography. For the 180 μm particles employed in this study, 77% of the water was converted to double hydrate over 72 h. Additional experiments were performed in which the ice particles were sequentially exposed to propane and then methane to make the double hydrate. However, this technique did not prove to be as efficient as exposure to the mixed gas. Finally, gas composition measurements during decomposition of the double hydrates reveal that the two gases are released simultaneously. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900027q [article] Toward the Efficient production of methane/propane double hydrate [texte imprimé] / Melissa R. Prado, Auteur ; Yazmin Cazares, Auteur ; Kenneth C. Janda, Auteur . - 2009 . - pp. 5160–5164. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N° 11 (Juin 2009) . - pp. 5160–5164 Mots-clés : Propane  hydrate  Methane  gas  Methane/propane  gas  mixture Résumé : Propane hydrate has been studied to investigate its use as a possible storage medium for methane gas. For practical purposes, hydrate formation needs to be efficient at near ambient conditions. Ice particles exposed to varying mixtures of propane and methane gas are found to form the double hydrate efficiently and may be quite effective for storing methane. For instance, exposure of the ice particles to a 2/1 methane/propane gas mixture for 18 h converts 66% of the ice to hydrate with 77% occupancy of the 512 cages and a final dissociation temperature of 287 K. The samples were then decomposed to determine the pressure versus temperature at a rate of 1 K/h. It was found that deviations from equilibrium were minor. The compositions of the hydrates were determined via gas chromatography. For the 180 μm particles employed in this study, 77% of the water was converted to double hydrate over 72 h. Additional experiments were performed in which the ice particles were sequentially exposed to propane and then methane to make the double hydrate. However, this technique did not prove to be as efficient as exposure to the mixed gas. Finally, gas composition measurements during decomposition of the double hydrates reveal that the two gases are released simultaneously. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900027q