Hydroformylation of 1-butene on Rh catalyst / Tapio Salmi in Industrial & engineering chemistry research, Vol. 48 N°3 (Février 2009)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 48 N°3 (Février 2009) . - p. 1325–1331 Titre : Hydroformylation of 1-butene on Rh catalyst Type de document : texte imprimé Auteurs : Tapio Salmi, Auteur ; Johan Ahlkvist, Auteur ; Andreas Bernas, Auteur Année de publication : 2009 Article en page(s) : p. 1325–1331 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Hydroformylation Rhodium catalyst Butene Résumé : Kinetics of homogeneously catalyzed hydroformylation of 1-butene was studied in a pressurized semibatch autoclave reactor. Kinetics was determined for a reaction mixture, which consisted of 1-butene, carbon monoxide, hydrogen, a rhodium-based catalyst, and 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate as a solvent. The following reaction parameters were investigated: temperature (70−100 °C), total pressure (1−3 MPa), catalyst concentration (100−200 ppm), catalyst (Rh)-to-ligand ratio, and the initial ratio of the synthesis gas (hydrogen and carbon dioxide) components. The solubility of 1-butene, carbon monoxide, and hydrogen in the solvent was determined by precise pressure and weight measurements and modeled mathematically. The main reaction products were pentanal (P) and 2-methylbutanal (MB), while trace amounts of cis-2- and trans-2-butene were detected as reaction intermediates. The ratio of the main products (P and MB) was practically independent of temperature, but the ligand-to-Rh ratio affected considerably the product distribution: an increasing ratio preferred the formation of pentanal (P). Increasing total pressure diminished the yield of pentanal (P). On the basis of the experimentally recorded kinetic data, a stoichiometric scheme was constructed and simplified. The kinetic data were combined with solubility models, and the parameters of an empirical power-law rate model were determined by nonlinear regression analysis. The kinetic parameters were well identified and physically reasonable being in accordance with qualitative observations. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie800215t [article] Hydroformylation of 1-butene on Rh catalyst [texte imprimé] / Tapio Salmi, Auteur ; Johan Ahlkvist, Auteur ; Andreas Bernas, Auteur . - 2009 . - p. 1325–1331. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N°3 (Février 2009) . - p. 1325–1331 Mots-clés : Hydroformylation Rhodium catalyst Butene Résumé : Kinetics of homogeneously catalyzed hydroformylation of 1-butene was studied in a pressurized semibatch autoclave reactor. Kinetics was determined for a reaction mixture, which consisted of 1-butene, carbon monoxide, hydrogen, a rhodium-based catalyst, and 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate as a solvent. The following reaction parameters were investigated: temperature (70−100 °C), total pressure (1−3 MPa), catalyst concentration (100−200 ppm), catalyst (Rh)-to-ligand ratio, and the initial ratio of the synthesis gas (hydrogen and carbon dioxide) components. The solubility of 1-butene, carbon monoxide, and hydrogen in the solvent was determined by precise pressure and weight measurements and modeled mathematically. The main reaction products were pentanal (P) and 2-methylbutanal (MB), while trace amounts of cis-2- and trans-2-butene were detected as reaction intermediates. The ratio of the main products (P and MB) was practically independent of temperature, but the ligand-to-Rh ratio affected considerably the product distribution: an increasing ratio preferred the formation of pentanal (P). Increasing total pressure diminished the yield of pentanal (P). On the basis of the experimentally recorded kinetic data, a stoichiometric scheme was constructed and simplified. The kinetic data were combined with solubility models, and the parameters of an empirical power-law rate model were determined by nonlinear regression analysis. The kinetic parameters were well identified and physically reasonable being in accordance with qualitative observations. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie800215t

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