Preparation and properties of microspherical alumina with a magnetic core/shell structure / Jun-Ting Feng in Industrial & engineering chemistry research, Vol. 48 N°2 (Janvier 2009)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 48 N°2 (Janvier 2009) . - p.692–697 Titre : Preparation and properties of microspherical alumina with a magnetic core/shell structure Type de document : texte imprimé Auteurs : Jun-Ting Feng, Auteur ; Lin, Yan-Jun, Auteur ; Feng Li, Auteur ; David G. Evans, Auteur Année de publication : 2009 Article en page(s) : p.692–697 Note générale : chemical engenireeng Langues : Anglais (eng) Mots-clés : Microspherical -- Alumina Résumé : A series of Ni2+−Co2+−Fe2+−Fe3+−SO42− layered double hydroxide precursors with different Ni/Co ratios have been synthesized by a method involving separate nucleation and aging steps. After calcination at 900 °C, the corresponding Ni1-xCoxFe oxides were obtained. Vibrating sample magnetometry indicated that the Ni1-xCoxFe oxide samples not only had high specific saturation magnetization, but also low coercivity and remanence. Ni1-xCoxFe oxides showed the optimum combination of magnetic properties for x = 0.2. Silica was coated onto the surface of Ni0.8Co0.2Fe oxide particles, and the coated particles were used as magnetic cores to prepare magnetic Ni0.8Co0.2Fe oxide/SiO2/γ-Al2O3 particles by hydrolysis of aluminum isopropoxide. After repeating the hydrolysis twice more, Ni0.8Co0.2Fe oxide/SiO2/γ-Al2O3 particles with about 20 wt % Ni0.8Co0.2Fe oxide were obtained and shown to be suitable for practical applications as a magnetic catalyst or catalyst support by virtue of their efficacious magnetic properties and pore structure. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie801098k [article] Preparation and properties of microspherical alumina with a magnetic core/shell structure [texte imprimé] / Jun-Ting Feng, Auteur ; Lin, Yan-Jun, Auteur ; Feng Li, Auteur ; David G. Evans, Auteur . - 2009 . - p.692–697. chemical engenireeng Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N°2 (Janvier 2009) . - p.692–697 Mots-clés : Microspherical -- Alumina Résumé : A series of Ni2+−Co2+−Fe2+−Fe3+−SO42− layered double hydroxide precursors with different Ni/Co ratios have been synthesized by a method involving separate nucleation and aging steps. After calcination at 900 °C, the corresponding Ni1-xCoxFe oxides were obtained. Vibrating sample magnetometry indicated that the Ni1-xCoxFe oxide samples not only had high specific saturation magnetization, but also low coercivity and remanence. Ni1-xCoxFe oxides showed the optimum combination of magnetic properties for x = 0.2. Silica was coated onto the surface of Ni0.8Co0.2Fe oxide particles, and the coated particles were used as magnetic cores to prepare magnetic Ni0.8Co0.2Fe oxide/SiO2/γ-Al2O3 particles by hydrolysis of aluminum isopropoxide. After repeating the hydrolysis twice more, Ni0.8Co0.2Fe oxide/SiO2/γ-Al2O3 particles with about 20 wt % Ni0.8Co0.2Fe oxide were obtained and shown to be suitable for practical applications as a magnetic catalyst or catalyst support by virtue of their efficacious magnetic properties and pore structure. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie801098k

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