Thermal stability and dispersion behavior of nanostructured CexZr1-xO2 mixed oxides over anatase-TiO2 / Benjaram M. Reddy in Industrial & engineering chemistry research, Vol. 48 N°1 (Janvier 2009)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 48 N°1 (Janvier 2009) . - P. 453-462 Titre : Thermal stability and dispersion behavior of nanostructured CexZr1-xO2 mixed oxides over anatase-TiO2 : a combined study of CO oxidation and characterization by XRD, XPS, TPR, HREM, and UV-Vis DRS Type de document : texte imprimé Auteurs : Benjaram M. Reddy, Éditeur scientifique ; Pankaj Bharali, Éditeur scientifique ; Pranjal Saikia, Éditeur scientifique Année de publication : 2009 Article en page(s) : P. 453-462 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Nanostructured CexZr1−  xO2 Thermal stability Oxides Anatase-TiO2 Résumé : A study has been undertaken on the thermal stability and dispersion behavior of nanostructured CexZr1−xO2 mixed oxides over anatase-TiO2 support, synthesized by a deposition coprecipitation method and subjected to heat treatments at different temperatures. An unsupported CexZr1−xO2 mixed oxide was also synthesized by coprecipitation method for the purpose of comparison. The structural/morphological characterization was performed using X-ray diffraction (XRD), high-resolution transmission electron microscopy (HREM), X-ray photoelectron spectroscopy (XPS), UV−visible diffuse reflectance spectroscopy (UV−vis DRS), and temperature-programmed reduction (TPR) techniques. XRD measurements revealed the presence of cubic Ce0.75Zr0.25O2 phase at 773 K and incorporation of more zirconium into the ceria lattice at higher temperatures. HREM analysis conformed highly dispersed Ce−Zr nano-oxides over anatase-TiO2 support having the sizes in the range of 3−5 nm at 773 K. At higher temperatures, a slight increase in the crystallite size (5−10 nm) has been observed. The XPS measurements revealed the stabilization of Ce3+ at higher temperatures and presence of Zr and Ti in 4+ oxidation states. UV−vis DRS studies showed that oxygen to metal (Ce4+/Ce3+) charge-transfer transitions occur at lower wavelengths in the case of CexZr1−xO2/TiO2 compared to pure CexZr1−xO2. TPR experiments revealed that the surface reduction of CexZr1−xO2/TiO2 takes place at lower temperatures, which facilitates better CO oxidation activity in comparison to the unsupported CexZr1−xO2. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8012677 [article] Thermal stability and dispersion behavior of nanostructured CexZr1-xO2 mixed oxides over anatase-TiO2 : a combined study of CO oxidation and characterization by XRD, XPS, TPR, HREM, and UV-Vis DRS [texte imprimé] / Benjaram M. Reddy, Éditeur scientifique ; Pankaj Bharali, Éditeur scientifique ; Pranjal Saikia, Éditeur scientifique . - 2009 . - P. 453-462. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N°1 (Janvier 2009) . - P. 453-462 Mots-clés : Nanostructured CexZr1−  xO2 Thermal stability Oxides Anatase-TiO2 Résumé : A study has been undertaken on the thermal stability and dispersion behavior of nanostructured CexZr1−xO2 mixed oxides over anatase-TiO2 support, synthesized by a deposition coprecipitation method and subjected to heat treatments at different temperatures. An unsupported CexZr1−xO2 mixed oxide was also synthesized by coprecipitation method for the purpose of comparison. The structural/morphological characterization was performed using X-ray diffraction (XRD), high-resolution transmission electron microscopy (HREM), X-ray photoelectron spectroscopy (XPS), UV−visible diffuse reflectance spectroscopy (UV−vis DRS), and temperature-programmed reduction (TPR) techniques. XRD measurements revealed the presence of cubic Ce0.75Zr0.25O2 phase at 773 K and incorporation of more zirconium into the ceria lattice at higher temperatures. HREM analysis conformed highly dispersed Ce−Zr nano-oxides over anatase-TiO2 support having the sizes in the range of 3−5 nm at 773 K. At higher temperatures, a slight increase in the crystallite size (5−10 nm) has been observed. The XPS measurements revealed the stabilization of Ce3+ at higher temperatures and presence of Zr and Ti in 4+ oxidation states. UV−vis DRS studies showed that oxygen to metal (Ce4+/Ce3+) charge-transfer transitions occur at lower wavelengths in the case of CexZr1−xO2/TiO2 compared to pure CexZr1−xO2. TPR experiments revealed that the surface reduction of CexZr1−xO2/TiO2 takes place at lower temperatures, which facilitates better CO oxidation activity in comparison to the unsupported CexZr1−xO2. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8012677

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