Simple procedure for interpreting hydrotreating kinetic data / K. T. Kam Ezra ; Hamza Al-Bazzaz ; Jamal Al-Fadhli in Industrial & engineering chemistry research, Vol. 47 n°22 (Novembre 2008)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 47 n°22 (Novembre 2008) . - p. 8594–8601 Titre : Simple procedure for interpreting hydrotreating kinetic data Type de document : texte imprimé Auteurs : K. T. Kam Ezra, Auteur ; Hamza Al-Bazzaz, Auteur ; Jamal Al-Fadhli, Auteur Année de publication : 2008 Article en page(s) : p. 8594–8601 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Hydrotreating Résumé : A simple procedure is developed to determine the apparent rate constants, reaction orders, and activation energies of various hydrotreating reactions, such as the hydrodesulfurization (HDS), hydrodemetalation (HDM), hydrodenitrogenation (HDN), and asphaltene cracking (HDAsph) of hydrotreating catalysts loaded in multiple-reactor fixed bed units. The procedure is derived from the basic kinetic and engineering principles. The only required input parameters are the sulfur, vanadium, nickel, nitrogen, and asphaltenes contents in the feedstock and products, reaction temperatures, and liquid hourly space velocity (LHSV). These parameters are normally available from laboratories performing the kinetic studies. Since there is no correlation coefficient in the developed kinetic expression, the apparent reaction rate constant and activation energy for various hydrotreating reactions can be determined directly once the optimum value of the reaction order has been identified. To demonstrate how the procedure works, it has been applied to calculate the kinetic values published in the open literature. Excellent agreements are obtained. The procedure is further verified with kinetic parameters from experiments undertaken in our pilot plants. In some cases, kinetic values which were unable to be determined in our pervious studies can now be obtained. The overall absolute average deviation (AAD) is less than 10%. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8002705 [article] Simple procedure for interpreting hydrotreating kinetic data [texte imprimé] / K. T. Kam Ezra, Auteur ; Hamza Al-Bazzaz, Auteur ; Jamal Al-Fadhli, Auteur . - 2008 . - p. 8594–8601. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 n°22 (Novembre 2008) . - p. 8594–8601 Mots-clés : Hydrotreating Résumé : A simple procedure is developed to determine the apparent rate constants, reaction orders, and activation energies of various hydrotreating reactions, such as the hydrodesulfurization (HDS), hydrodemetalation (HDM), hydrodenitrogenation (HDN), and asphaltene cracking (HDAsph) of hydrotreating catalysts loaded in multiple-reactor fixed bed units. The procedure is derived from the basic kinetic and engineering principles. The only required input parameters are the sulfur, vanadium, nickel, nitrogen, and asphaltenes contents in the feedstock and products, reaction temperatures, and liquid hourly space velocity (LHSV). These parameters are normally available from laboratories performing the kinetic studies. Since there is no correlation coefficient in the developed kinetic expression, the apparent reaction rate constant and activation energy for various hydrotreating reactions can be determined directly once the optimum value of the reaction order has been identified. To demonstrate how the procedure works, it has been applied to calculate the kinetic values published in the open literature. Excellent agreements are obtained. The procedure is further verified with kinetic parameters from experiments undertaken in our pilot plants. In some cases, kinetic values which were unable to be determined in our pervious studies can now be obtained. The overall absolute average deviation (AAD) is less than 10%. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8002705

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