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Efficiency of amine-modified poly(glycidyl methacrylate)-grafted cellulose in the removal and recovery of vanadium(V) from aqueous solutions / T. S. Anirudhan in Industrial & engineering chemistry research, Vol. 48 N°4 (Février 2009) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 48 N°4 (Février 2009) . - p. 2118–2124 Titre : Efficiency of amine-modified poly(glycidyl methacrylate)-grafted cellulose in the removal and recovery of vanadium(V) from aqueous solutions Type de document : texte imprimé Auteurs : T. S. Anirudhan, Auteur ; S. Jalajamony, Auteur ; L. Divya, Auteur Année de publication : 2009 Article en page(s) : p. 2118–2124 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Cellulose  anion  exchanger  Glycidyl  methacrylate  Hydrochloric  acid  treatment Résumé : A cellulose-based anion exchanger (Cell-AE) bearing the —N+HR2Cl− functional group was prepared through graft copolymerization of glycidyl methacrylate onto cellulose (Cell) in the presence of N,N′-methylenebisacrylamide as a cross-linker using benzoyl peroxide as the initiator, followed by amination and hydrochloric acid treatment. The adsorbent was characterized by infrared spectroscopy, scanning electron microscopy, surface area analysis, thermogravimetry, and potentiometric titrations. Batch experiments were performed to evaluate the adsorption efficiency of Cell-AE toward V(V) ions in aqueous solutions. The maximum removal was observed in the pH range of 4.0−6.0. The adsorption process achieved more than 99.6% V(V) removal from an initial concentration of 25.0 mg/L. Adsorption kinetic data were described by pseudo-second-order equation. The equilibrium data fitted very well with the Langmuir model, and the maximum adsorption capacity of Cell-AE toward V(V) was found to be 197.75 mg/g at 30 °C. Over 96.0% desorption of V(V) was achieved with 0.1 M NaOH solution. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8000869 [article] Efficiency of amine-modified poly(glycidyl methacrylate)-grafted cellulose in the removal and recovery of vanadium(V) from aqueous solutions [texte imprimé] / T. S. Anirudhan, Auteur ; S. Jalajamony, Auteur ; L. Divya, Auteur . - 2009 . - p. 2118–2124. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N°4 (Février 2009) . - p. 2118–2124 Mots-clés : Cellulose  anion  exchanger  Glycidyl  methacrylate  Hydrochloric  acid  treatment Résumé : A cellulose-based anion exchanger (Cell-AE) bearing the —N+HR2Cl− functional group was prepared through graft copolymerization of glycidyl methacrylate onto cellulose (Cell) in the presence of N,N′-methylenebisacrylamide as a cross-linker using benzoyl peroxide as the initiator, followed by amination and hydrochloric acid treatment. The adsorbent was characterized by infrared spectroscopy, scanning electron microscopy, surface area analysis, thermogravimetry, and potentiometric titrations. Batch experiments were performed to evaluate the adsorption efficiency of Cell-AE toward V(V) ions in aqueous solutions. The maximum removal was observed in the pH range of 4.0−6.0. The adsorption process achieved more than 99.6% V(V) removal from an initial concentration of 25.0 mg/L. Adsorption kinetic data were described by pseudo-second-order equation. The equilibrium data fitted very well with the Langmuir model, and the maximum adsorption capacity of Cell-AE toward V(V) was found to be 197.75 mg/g at 30 °C. Over 96.0% desorption of V(V) was achieved with 0.1 M NaOH solution. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8000869