Anodic degradation of CI reactive blue 221 using graphite and IrO2/TaO2/RuO2 coated titanium electrodes / M. Thalamadai Karuppiah in Industrial & engineering chemistry research, Vol. 48 N°4 (Février 2009)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 48 N°4 (Février 2009) . - p. 2149–2156 Titre : Anodic degradation of CI reactive blue 221 using graphite and IrO2/TaO2/RuO2 coated titanium electrodes Type de document : texte imprimé Auteurs : M. Thalamadai Karuppiah, Auteur ; G. Bhaskar Raju, Auteur Année de publication : 2009 Article en page(s) : p. 2149–2156 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : CI reactive blue Biorecalcitrant dye Coated titanium electrodes Chemical oxygen demand Spectrophotometric method Organic carbon measurements Résumé : Anodic degradation of the biorecalcitrant reactive dye CI Reactive Blue 221 was investigated using graphite and IrO2/TaO2/RuO2 coated titanium electrodes in a batch reactor setup. The decolorization and mineralization of the dye molecule was monitored by UV−visible spectrophotometric method and chemical oxygen demand (COD) and/or total organic carbon (TOC) measurements, respectively. The effect of different electrolytes and applied current density on the mineralization of CI Reactive Blue 221 in the presence of different electrode materials was studied. Though both the electrode materials were found to be effective for decolorization, complete mineralization of the dye was accomplished in the presence of graphite over a pH range of 6.0−8.0. The efficiency of the electrode material was evaluated in terms of instantaneous current efficiency (ICE), electrochemical oxidizability index (EOI), and specific energy consumption (Esp). The metabolites formed during the degradation reaction were identified using GC-MS, and the degradation pathway was proposed. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie801291h [article] Anodic degradation of CI reactive blue 221 using graphite and IrO2/TaO2/RuO2 coated titanium electrodes [texte imprimé] / M. Thalamadai Karuppiah, Auteur ; G. Bhaskar Raju, Auteur . - 2009 . - p. 2149–2156. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N°4 (Février 2009) . - p. 2149–2156 Mots-clés : CI reactive blue Biorecalcitrant dye Coated titanium electrodes Chemical oxygen demand Spectrophotometric method Organic carbon measurements Résumé : Anodic degradation of the biorecalcitrant reactive dye CI Reactive Blue 221 was investigated using graphite and IrO2/TaO2/RuO2 coated titanium electrodes in a batch reactor setup. The decolorization and mineralization of the dye molecule was monitored by UV−visible spectrophotometric method and chemical oxygen demand (COD) and/or total organic carbon (TOC) measurements, respectively. The effect of different electrolytes and applied current density on the mineralization of CI Reactive Blue 221 in the presence of different electrode materials was studied. Though both the electrode materials were found to be effective for decolorization, complete mineralization of the dye was accomplished in the presence of graphite over a pH range of 6.0−8.0. The efficiency of the electrode material was evaluated in terms of instantaneous current efficiency (ICE), electrochemical oxidizability index (EOI), and specific energy consumption (Esp). The metabolites formed during the degradation reaction were identified using GC-MS, and the degradation pathway was proposed. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie801291h

Exemplaires

Code-barres	Cote	Support	Localisation	Section	Disponibilité
aucun exemplaire