Preparation and characterization of a selective nitric oxide adsorbent based on cobalt(II) phthalocyanine tetrasulfonic acid / W. J. Desisto in Industrial & engineering chemistry research, Vol. 47 N°20 (Octobre 2008)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 47 N°20 (Octobre 2008) . - P. 7857-7861 Titre : Preparation and characterization of a selective nitric oxide adsorbent based on cobalt(II) phthalocyanine tetrasulfonic acid Type de document : texte imprimé Auteurs : W. J. Desisto, Auteur ; R. Cashon, Auteur ; D. Cassidy, Auteur ; N. Hill, Auteur Année de publication : 2008 Article en page(s) : P. 7857-7861 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Nitric oxide (NO) cobalt(II) phthalocyanine tetrasulfonic acid (CoPcS Résumé : We report the synthesis and characterization of a selective nitric oxide (NO) adsorbent based on the covalent binding of cobalt(II) phthalocyanine tetrasulfonic acid (CoPcS) onto imidazole-functionalized mesoporous silica gel beads. The equilibrium data indicated that the adsorption of NO was highly favorable, approaching irreversible adsorption. The breakthrough curves for NO were modeled assuming irreversible adsorption and resulted in pore diffusivities through the packed bed of 0.1−0.3 cm2·s−1. Adsorption experiments of NO in the presence of nitrogen, water vapor, and ammonia indicated that the adsorption was selective for NO. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8000293 [article] Preparation and characterization of a selective nitric oxide adsorbent based on cobalt(II) phthalocyanine tetrasulfonic acid [texte imprimé] / W. J. Desisto, Auteur ; R. Cashon, Auteur ; D. Cassidy, Auteur ; N. Hill, Auteur . - 2008 . - P. 7857-7861. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 N°20 (Octobre 2008) . - P. 7857-7861 Mots-clés : Nitric oxide (NO) cobalt(II) phthalocyanine tetrasulfonic acid (CoPcS Résumé : We report the synthesis and characterization of a selective nitric oxide (NO) adsorbent based on the covalent binding of cobalt(II) phthalocyanine tetrasulfonic acid (CoPcS) onto imidazole-functionalized mesoporous silica gel beads. The equilibrium data indicated that the adsorption of NO was highly favorable, approaching irreversible adsorption. The breakthrough curves for NO were modeled assuming irreversible adsorption and resulted in pore diffusivities through the packed bed of 0.1−0.3 cm2·s−1. Adsorption experiments of NO in the presence of nitrogen, water vapor, and ammonia indicated that the adsorption was selective for NO. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8000293

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