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Comparison of corresponding-states-based correlations for the prediction of the vaporization enthalpy of fluids / Angel Mulero in Industrial & engineering chemistry research, Vol. 47 N°20 (Octobre 2008) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 47 N°20 (Octobre 2008) . - P. 7903-7916 Titre : Comparison of corresponding-states-based correlations for the prediction of the vaporization enthalpy of fluids Type de document : texte imprimé Auteurs : Angel Mulero, Auteur ; Isidro Cachadina, Auteur ; M. I. Parra, Auteur Année de publication : 2008 Article en page(s) : P. 7903-7916 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Analytical  correlations  vaporization  of  fluids  DIPPR  project Résumé : Four analytical correlations, including one proposed very recently, were used to calculate the enthalpy of vaporization of fluids. These correlations are based on the Pitzer et al. corresponding states principle and require as input the critical temperature and the acentric factor. They have generally been applied only to a reduced number of normal fluids (nonpolar, slightly polar, non-hydrogen-bonding, and nonquantum fluids), but in this paper we check their accuracy and applicability for 1594 polar and nonpolar fluids grouped into 81 families. The results are compared with the values accepted by the DIPPR project. Recommendations are given for the use of each model and for the choice of the adequate model for each family of fluids. In particular, we found that the most recent model, proposed by Morgan, gives the best results for most of the families and behaves better than the other models at both high and low temperatures. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie800557q [article] Comparison of corresponding-states-based correlations for the prediction of the vaporization enthalpy of fluids [texte imprimé] / Angel Mulero, Auteur ; Isidro Cachadina, Auteur ; M. I. Parra, Auteur . - 2008 . - P. 7903-7916. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 N°20 (Octobre 2008) . - P. 7903-7916 Mots-clés : Analytical  correlations  vaporization  of  fluids  DIPPR  project Résumé : Four analytical correlations, including one proposed very recently, were used to calculate the enthalpy of vaporization of fluids. These correlations are based on the Pitzer et al. corresponding states principle and require as input the critical temperature and the acentric factor. They have generally been applied only to a reduced number of normal fluids (nonpolar, slightly polar, non-hydrogen-bonding, and nonquantum fluids), but in this paper we check their accuracy and applicability for 1594 polar and nonpolar fluids grouped into 81 families. The results are compared with the values accepted by the DIPPR project. Recommendations are given for the use of each model and for the choice of the adequate model for each family of fluids. In particular, we found that the most recent model, proposed by Morgan, gives the best results for most of the families and behaves better than the other models at both high and low temperatures. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie800557q