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Syngas production from catalytic partial oxidation of n-butane / Rainer J. Bass in Industrial & engineering chemistry research, Vol. 47 N°19 (Octobre 2008) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 47 N°19 (Octobre 2008) . - p. 7184–7189 Titre : Syngas production from catalytic partial oxidation of n-butane : comparison between incipient wetness and sol-gel prepared Pt/Al2O3 Type de document : texte imprimé Auteurs : Rainer J. Bass, Auteur ; Timothy M. Dunn, Auteur ; Yu-Chuan Lin, Auteur Année de publication : 2008 Article en page(s) : p. 7184–7189 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : n-butane  Catalytic  partial  oxidation  Sol-gel  catalyst  Incipient  wetness  catalyst Résumé : Catalytic partial oxidation (CPO) of n-butane under autothermal condition was studied over both incipient wetness (IW) and sol−gel (SG) prepared Pt/Al2O3 catalysts. These catalysts gave different results, with SG Pt/Al2O3 producing more H2 and CO than IW Pt/Al2O3 under the same reaction conditions. The difference between these two may be attributed to the particle size of platinum: the observed Pt particle sizes on both freshly prepared and used SG Pt/Al2O3 was 50% smaller than those on IW Pt/Al2O3. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8007506 [article] Syngas production from catalytic partial oxidation of n-butane : comparison between incipient wetness and sol-gel prepared Pt/Al2O3 [texte imprimé] / Rainer J. Bass, Auteur ; Timothy M. Dunn, Auteur ; Yu-Chuan Lin, Auteur . - 2008 . - p. 7184–7189. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 N°19 (Octobre 2008) . - p. 7184–7189 Mots-clés : n-butane  Catalytic  partial  oxidation  Sol-gel  catalyst  Incipient  wetness  catalyst Résumé : Catalytic partial oxidation (CPO) of n-butane under autothermal condition was studied over both incipient wetness (IW) and sol−gel (SG) prepared Pt/Al2O3 catalysts. These catalysts gave different results, with SG Pt/Al2O3 producing more H2 and CO than IW Pt/Al2O3 under the same reaction conditions. The difference between these two may be attributed to the particle size of platinum: the observed Pt particle sizes on both freshly prepared and used SG Pt/Al2O3 was 50% smaller than those on IW Pt/Al2O3. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8007506