Direct Chlorination of Nickel-Containing Materials. Recovery of the Metal from Different Sources / J. F. Álvarez in Industrial & engineering chemistry research, Vol. 47 n°21 (Novembre 2008)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 47 n°21 (Novembre 2008) . - p. 8184–8191 Titre : Direct Chlorination of Nickel-Containing Materials. Recovery of the Metal from Different Sources Type de document : texte imprimé Auteurs : J. F. Álvarez, Auteur ; Ana E. Bohé, Auteur Année de publication : 2008 Article en page(s) : p. 8184–8191 Note générale : chemical engineering Langues : Anglais (eng) Mots-clés : Chlorination of nickel Résumé : In the present work, the chlorination of nickel-containing materials is proposed: using NiO and mixtures that simulate the conditions of 12 wt % NiO−Al2O3 catalyst, prepared by mechanical mixing and incipient wetness impregnation (IWI), the reaction with gaseous chlorine proceeds from 500 to 800 °C. Non-isothermal experiments from 20 to 950 °C and isothermal measurements at 725, 800, and 850 °C were performed under Ar−Cl2 atmosphere in a thermogravimetric (TG) system. Direct chlorination of the mixtures was carried out isothermally in a tubular reactor under a flow of Cl2 from 500 to 800 °C. The chlorination started at 725, 473, and 428 °C for NiO, the mechanical mixture, and the IWI mixture, respectively. The high temperature for NiO can be explained by its BET area, which is small enough to reduce the reactivity of the sample. The recovery factor of Ni from Al2O3 attained at 800 °C was 85% for the mechanical mixture and 96% for the IWI mixture. All the species were characterized by X-ray diffraction (XRD), scanning-electron microscopy (SEM), and energy-dispersive spectroscopy (EDS) techniques. They were quantified by X-ray fluorescence spectrometry (XRF), and BET surface area (BET) was measured in the samples. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8006598 [article] Direct Chlorination of Nickel-Containing Materials. Recovery of the Metal from Different Sources [texte imprimé] / J. F. Álvarez, Auteur ; Ana E. Bohé, Auteur . - 2008 . - p. 8184–8191. chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 n°21 (Novembre 2008) . - p. 8184–8191 Mots-clés : Chlorination of nickel Résumé : In the present work, the chlorination of nickel-containing materials is proposed: using NiO and mixtures that simulate the conditions of 12 wt % NiO−Al2O3 catalyst, prepared by mechanical mixing and incipient wetness impregnation (IWI), the reaction with gaseous chlorine proceeds from 500 to 800 °C. Non-isothermal experiments from 20 to 950 °C and isothermal measurements at 725, 800, and 850 °C were performed under Ar−Cl2 atmosphere in a thermogravimetric (TG) system. Direct chlorination of the mixtures was carried out isothermally in a tubular reactor under a flow of Cl2 from 500 to 800 °C. The chlorination started at 725, 473, and 428 °C for NiO, the mechanical mixture, and the IWI mixture, respectively. The high temperature for NiO can be explained by its BET area, which is small enough to reduce the reactivity of the sample. The recovery factor of Ni from Al2O3 attained at 800 °C was 85% for the mechanical mixture and 96% for the IWI mixture. All the species were characterized by X-ray diffraction (XRD), scanning-electron microscopy (SEM), and energy-dispersive spectroscopy (EDS) techniques. They were quantified by X-ray fluorescence spectrometry (XRF), and BET surface area (BET) was measured in the samples. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8006598

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