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Room temperature ionic liquids for mercury capture from flue gas / Lei Ji in Industrial & engineering chemistry research, Vol. 47 n°21 (Novembre 2008) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 47 n°21 (Novembre 2008) . - p. 8396–8400 Titre : Room temperature ionic liquids for mercury capture from flue gas Type de document : texte imprimé Auteurs : Lei Ji, Auteur ; Stephen W Thiel, Auteur ; neville G. Pinto, Auteur Année de publication : 2008 Article en page(s) : p. 8396–8400 Note générale : Chemical engineering Langues : Anglais (eng) Résumé : Six room temperature ionic liquids (RTILs) were synthesized and tested as coatings for adsorbents for mercury capture from nitrogen at 160 °C. All six RTILs were thermally stable to temperatures above 160 °C. These RTILs were coated on mesoporous silica gel, and the fixed-bed mercury capture characteristics of these adsorbents were observed at 160 °C. Hg0 capture appears to result from the formation of a complex involving Hg0 and ions in the RTIL complex, and not from oxidation by the RTIL. The high observed oxidized mercury capacity for Cl−-based RTILs is believed to be due to greater dissociation of HgCl2 in the RTILs that incorporate chloride anion. The higher hydrogen-bond basicity and dipolarity of these RTILs might underlie improved HgCl2 dissociation. [bmim]Cl was identified as a promising RTIL for the simultaneous capture of elemental and oxidized mercury from the gas phase. A nanostructured chelating adsorbent with a coating of 25 wt % [bmim]Cl has an elemental mercury capacity of 10 mg/g and an oxidized mercury capacity of at least 38 mg/g. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8008023 [article] Room temperature ionic liquids for mercury capture from flue gas [texte imprimé] / Lei Ji, Auteur ; Stephen W Thiel, Auteur ; neville G. Pinto, Auteur . - 2008 . - p. 8396–8400. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 n°21 (Novembre 2008) . - p. 8396–8400 Résumé : Six room temperature ionic liquids (RTILs) were synthesized and tested as coatings for adsorbents for mercury capture from nitrogen at 160 °C. All six RTILs were thermally stable to temperatures above 160 °C. These RTILs were coated on mesoporous silica gel, and the fixed-bed mercury capture characteristics of these adsorbents were observed at 160 °C. Hg0 capture appears to result from the formation of a complex involving Hg0 and ions in the RTIL complex, and not from oxidation by the RTIL. The high observed oxidized mercury capacity for Cl−-based RTILs is believed to be due to greater dissociation of HgCl2 in the RTILs that incorporate chloride anion. The higher hydrogen-bond basicity and dipolarity of these RTILs might underlie improved HgCl2 dissociation. [bmim]Cl was identified as a promising RTIL for the simultaneous capture of elemental and oxidized mercury from the gas phase. A nanostructured chelating adsorbent with a coating of 25 wt % [bmim]Cl has an elemental mercury capacity of 10 mg/g and an oxidized mercury capacity of at least 38 mg/g. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie8008023