Impact of kraft process modifications on eucalyptus globulus pulping performance and polysaccharide retention / Ana Sofia Santiago in Industrial & engineering chemistry research, Vol. 47 N°19 (Octobre 2008)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 47 N°19 (Octobre 2008) . - p. 7433–7440 Titre : Impact of kraft process modifications on eucalyptus globulus pulping performance and polysaccharide retention Type de document : texte imprimé Auteurs : Ana Sofia Santiago, Auteur ; Carlos Pascoal Neto, Auteur Année de publication : 2008 Article en page(s) : p. 7433–7440 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Alkali Anthraquinone Eucalyptus globulus kraft Résumé : The impact of effective alkali (EA) splitting and anthraquinone (AQ) addition on Eucalyptus globulus kraft pulping yield and pulp quality was investigated. AQ addition to kraft pulping enhances the rate of delignification, leading to alkali saving and reducing time at maximum temperature. A 1.9% total yield increase was observed, assigned to the enhancement of both cellulose and xylan retention but also due an increase of rejects content. Contrary to results described in the literature for other woods, the use of an even effective alkali concentration profile throughout the cook of E. globulus did not affect pulp yield or carbohydrate composition of screened pulp. However, EA profiling resulted in a higher pulp viscosity, indicating a lower degradation of cellulose chains along the pulping. Such results were interpreted taking into account the peculiar chemical structure of E. globulus wood components. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie071488g [article] Impact of kraft process modifications on eucalyptus globulus pulping performance and polysaccharide retention [texte imprimé] / Ana Sofia Santiago, Auteur ; Carlos Pascoal Neto, Auteur . - 2008 . - p. 7433–7440. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 N°19 (Octobre 2008) . - p. 7433–7440 Mots-clés : Alkali Anthraquinone Eucalyptus globulus kraft Résumé : The impact of effective alkali (EA) splitting and anthraquinone (AQ) addition on Eucalyptus globulus kraft pulping yield and pulp quality was investigated. AQ addition to kraft pulping enhances the rate of delignification, leading to alkali saving and reducing time at maximum temperature. A 1.9% total yield increase was observed, assigned to the enhancement of both cellulose and xylan retention but also due an increase of rejects content. Contrary to results described in the literature for other woods, the use of an even effective alkali concentration profile throughout the cook of E. globulus did not affect pulp yield or carbohydrate composition of screened pulp. However, EA profiling resulted in a higher pulp viscosity, indicating a lower degradation of cellulose chains along the pulping. Such results were interpreted taking into account the peculiar chemical structure of E. globulus wood components. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie071488g

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