[article]
Titre : |
Catalytic hydrotreatment of crude waxes from different sources over a Ni-W/-Al2O3 catalyst |
Type de document : |
texte imprimé |
Auteurs : |
Jesús Sánchez, Auteur ; María Fernanda Tallafigo, Auteur ; Miguel A. Gilarranz, Auteur |
Année de publication : |
2008 |
Article en page(s) : |
p. 6854–6861 |
Note générale : |
Chemical engineering |
Langues : |
Anglais (eng) |
Mots-clés : |
Crude wax Alumina-supported catalyst Spindle feedstock |
Résumé : |
The hydrotreatment of crude wax from the dewaxing of spindle, light neutral, medium neutral, heavy neutral, and brightstock oil was studied to obtain refined paraffins that are suitable for high-grade applications. The runs were performed using an alumina-supported catalyst with 5.9 wt % of nickel (as NiO) and 16.2 wt % of tungsten (as WO3) that was used for >6000 h. The ease of treatment was ranked as follows: spindle > light neutral > medium neutral > heavy neutral ≫ brightstock. The use of high temperatures and pressures was needed to obtain a convenient reduction in the color of the heavier feedstocks. Spindle feedstock required a temperature of 548 K and a pressure of 9.81 MPa, whereas 623 K and 13.7 MPa were needed for heavy neutral feedstock to obtain refined paraffins with a Saybolt color of >+30. |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie800014u |
in Industrial & engineering chemistry research > Vol. 47 N°18 (Septembre 2008) . - p. 6854–6861
[article] Catalytic hydrotreatment of crude waxes from different sources over a Ni-W/-Al2O3 catalyst [texte imprimé] / Jesús Sánchez, Auteur ; María Fernanda Tallafigo, Auteur ; Miguel A. Gilarranz, Auteur . - 2008 . - p. 6854–6861. Chemical engineering Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 47 N°18 (Septembre 2008) . - p. 6854–6861
Mots-clés : |
Crude wax Alumina-supported catalyst Spindle feedstock |
Résumé : |
The hydrotreatment of crude wax from the dewaxing of spindle, light neutral, medium neutral, heavy neutral, and brightstock oil was studied to obtain refined paraffins that are suitable for high-grade applications. The runs were performed using an alumina-supported catalyst with 5.9 wt % of nickel (as NiO) and 16.2 wt % of tungsten (as WO3) that was used for >6000 h. The ease of treatment was ranked as follows: spindle > light neutral > medium neutral > heavy neutral ≫ brightstock. The use of high temperatures and pressures was needed to obtain a convenient reduction in the color of the heavier feedstocks. Spindle feedstock required a temperature of 548 K and a pressure of 9.81 MPa, whereas 623 K and 13.7 MPa were needed for heavy neutral feedstock to obtain refined paraffins with a Saybolt color of >+30. |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie800014u |
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