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Strategies for the design of hydrophilic microspheres with controlled size and microstructure / Huanhuan Qu in Industrial & engineering chemistry research, Vol. 47 N°17 (Septembre 2008) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 47 N°17 (Septembre 2008) . - p. 6399–6404 Titre : Strategies for the design of hydrophilic microspheres with controlled size and microstructure Type de document : texte imprimé Auteurs : Huanhuan Qu, Auteur ; Fangling Gong, Auteur ; Jing Wang, Auteur Année de publication : 2008 Article en page(s) : p. 6399–6404 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Hydrophilic  microspheres  Membrane  emulsification  Droplets  swelling  method  PHEMA  microspheres Résumé : Synthesizing hydrophilic microspheres is a subject of great interest for a variety of applications. However, there is difficulty in the control of the microspheresʼ size. In this study, the combination of membrane emulsification and droplets swelling method is utilized to prepare poly(2-hydroxyethylmethacrylate) (PHEMA) microspheres, a kind of hydrophilic material. The former is used to prepare monodisperse seed droplets, which include hydrophobic monomer (ethylenedimethacrylate, EDMA) and some assistant agents, whereas the latter is used for the absorption of hydrophilic monomer (HEMA). After a polymerization process, PHEMA microspheres with desired size can be obtained. It is found that large membrane pore size or high swelling ratio tended to increase the final particle size. At the same time, smaller particle size is got at higher EDMA concentration in the seed droplets. In addition, microstructure of the microspheres is also controlled by using this method. Nonporous, porous, nonporous/porous half-moon, or macroporous microspheres can be obtained easily by changing the total oil composition in swollen droplets. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie800094a [article] Strategies for the design of hydrophilic microspheres with controlled size and microstructure [texte imprimé] / Huanhuan Qu, Auteur ; Fangling Gong, Auteur ; Jing Wang, Auteur . - 2008 . - p. 6399–6404. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 N°17 (Septembre 2008) . - p. 6399–6404 Mots-clés : Hydrophilic  microspheres  Membrane  emulsification  Droplets  swelling  method  PHEMA  microspheres Résumé : Synthesizing hydrophilic microspheres is a subject of great interest for a variety of applications. However, there is difficulty in the control of the microspheresʼ size. In this study, the combination of membrane emulsification and droplets swelling method is utilized to prepare poly(2-hydroxyethylmethacrylate) (PHEMA) microspheres, a kind of hydrophilic material. The former is used to prepare monodisperse seed droplets, which include hydrophobic monomer (ethylenedimethacrylate, EDMA) and some assistant agents, whereas the latter is used for the absorption of hydrophilic monomer (HEMA). After a polymerization process, PHEMA microspheres with desired size can be obtained. It is found that large membrane pore size or high swelling ratio tended to increase the final particle size. At the same time, smaller particle size is got at higher EDMA concentration in the seed droplets. In addition, microstructure of the microspheres is also controlled by using this method. Nonporous, porous, nonporous/porous half-moon, or macroporous microspheres can be obtained easily by changing the total oil composition in swollen droplets. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie800094a