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Pyrolytic decarboxylation and cracking of stearic acid / Kelly D. Maher in Industrial & engineering chemistry research, Vol. 47 n°15 (Août 2008) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 47 n°15 (Août 2008) . - p. 5328–5336 Titre : Pyrolytic decarboxylation and cracking of stearic acid Type de document : texte imprimé Auteurs : Kelly D. Maher, Auteur ; Kathlyn M. Kirkwood, Auteur ; Murray R. Gray, Auteur ; David C. Bressler, Auteur Année de publication : 2008 Article en page(s) : p. 5328–5336 Note générale : Bibliogr. p. 5335-5336 Langues : Anglais (eng) Mots-clés : Fatty  acids  --  pyrolytic  conversion;  Decarboxylation;  Stearic  acid Résumé : The primary objective of this work was to study the pyrolytic conversion of fatty acids to produce deoxygenated, liquid hydrocarbon products for use as renewable chemicals or fuels. Stearic acid (n-octadecanoic acid) was chosen as a model compound for the free fatty acids liberated through the hydrolysis of beef tallow. Batch pyrolysis of stearic acid was conducted over a range of temperatures and times, and the reaction products were extracted and identified through gas chromatography and mass spectrometry. Under mild conditions, n-heptadecane was the main product, with concurrent production of CO2, showing that decarboxylation was likely the first reaction to occur. Distinct series of n-alkanes and 1-alkenes developed and shifted to lower carbon numbers with increased temperature and time, consistent with hydrocarbon cracking reactions. Eventually, the series decomposed to aromatics, insoluble solids, and unidentified low-molecular-weight species. Semiquantitative analysis of the chromatographic data confirmed the predominance of n-heptadecane in the product mixture, the development and decomposition of the aliphatic species, the selectivity for n-alkanes over 1-alkenes, and the shift in product distribution toward lower carbon numbers. This work demonstrates the feasibility of producing liquid hydrocarbons through the pyrolysis of free fatty acids hydrolyzed from lipid feeds. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie0714551 [article] Pyrolytic decarboxylation and cracking of stearic acid [texte imprimé] / Kelly D. Maher, Auteur ; Kathlyn M. Kirkwood, Auteur ; Murray R. Gray, Auteur ; David C. Bressler, Auteur . - 2008 . - p. 5328–5336. Bibliogr. p. 5335-5336 Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 n°15 (Août 2008) . - p. 5328–5336 Mots-clés : Fatty  acids  --  pyrolytic  conversion;  Decarboxylation;  Stearic  acid Résumé : The primary objective of this work was to study the pyrolytic conversion of fatty acids to produce deoxygenated, liquid hydrocarbon products for use as renewable chemicals or fuels. Stearic acid (n-octadecanoic acid) was chosen as a model compound for the free fatty acids liberated through the hydrolysis of beef tallow. Batch pyrolysis of stearic acid was conducted over a range of temperatures and times, and the reaction products were extracted and identified through gas chromatography and mass spectrometry. Under mild conditions, n-heptadecane was the main product, with concurrent production of CO2, showing that decarboxylation was likely the first reaction to occur. Distinct series of n-alkanes and 1-alkenes developed and shifted to lower carbon numbers with increased temperature and time, consistent with hydrocarbon cracking reactions. Eventually, the series decomposed to aromatics, insoluble solids, and unidentified low-molecular-weight species. Semiquantitative analysis of the chromatographic data confirmed the predominance of n-heptadecane in the product mixture, the development and decomposition of the aliphatic species, the selectivity for n-alkanes over 1-alkenes, and the shift in product distribution toward lower carbon numbers. This work demonstrates the feasibility of producing liquid hydrocarbons through the pyrolysis of free fatty acids hydrolyzed from lipid feeds. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie0714551