Effect of catalysts supporting on tandem polymerization of ethylene stock in synthesis ofethylene-1-hexene copolymer / Junwei Zhang in Industrial & engineering chemistry research, Vol. 47 n°15 (Août 2008)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 47 n°15 (Août 2008) . - p. 5369-5375 Titre : Effect of catalysts supporting on tandem polymerization of ethylene stock in synthesis ofethylene-1-hexene copolymer Type de document : texte imprimé Auteurs : Junwei Zhang, Auteur ; Hong Fan, Auteur ; Bo-Geng Li, Auteur ; Shiping Zhu, Auteur Année de publication : 2008 Article en page(s) : p. 5369-5375 Note générale : Bibliogr. p. 5374-5375 Langues : Anglais (eng) Mots-clés : Ethylene stock  Copolymérisation  polyéthylène Résumé : Ethylene-1-hexene copolymers were synthesized with a tandem catalysis system consisting of a new trimerization catalyst (1), bis(2-dodecylsulfanylethyl)amine-CrCl3, and a copolymerization catalyst (2), Et(Ind)2ZrCl2. Catalysts 1 and 2 were supported on silica particles, and the effects of different supporting strategies on trimerization selectivity, 1-hexene incorporation efficiency, and copolymerization activity were studied and compared to the homogeneous system. It was found that the supported 1 trimerized ethylene with a similar selectivity (>99%) but one-quarter of the activity of the homogeneous 1. The supported 2 gave 40% 1-hexene incorporation efficiency and one-third of the copolymerization activity of the homogeneous 2. The tandem action of the supported 1 and 2 yielded linear low-density polyethylene (LLDPE) materials that contained only C4 side-chains. The dual supported system had activities at a 107 g/(mol Zr h) level, in the same order of the homogeneous counterpart. Adjusting the Cr/Zr ratio yielded various branching densities and, thus, melting temperatures of the resulting polymers. The samples prepared with the supported 2 exhibited broad differential scanning calorimetry (DSC) curves, probably due to multiple active sites. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie7017564 [article] Effect of catalysts supporting on tandem polymerization of ethylene stock in synthesis ofethylene-1-hexene copolymer [texte imprimé] / Junwei Zhang, Auteur ; Hong Fan, Auteur ; Bo-Geng Li, Auteur ; Shiping Zhu, Auteur . - 2008 . - p. 5369-5375. Bibliogr. p. 5374-5375 Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 n°15 (Août 2008) . - p. 5369-5375 Mots-clés : Ethylene stock  Copolymérisation  polyéthylène Résumé : Ethylene-1-hexene copolymers were synthesized with a tandem catalysis system consisting of a new trimerization catalyst (1), bis(2-dodecylsulfanylethyl)amine-CrCl3, and a copolymerization catalyst (2), Et(Ind)2ZrCl2. Catalysts 1 and 2 were supported on silica particles, and the effects of different supporting strategies on trimerization selectivity, 1-hexene incorporation efficiency, and copolymerization activity were studied and compared to the homogeneous system. It was found that the supported 1 trimerized ethylene with a similar selectivity (>99%) but one-quarter of the activity of the homogeneous 1. The supported 2 gave 40% 1-hexene incorporation efficiency and one-third of the copolymerization activity of the homogeneous 2. The tandem action of the supported 1 and 2 yielded linear low-density polyethylene (LLDPE) materials that contained only C4 side-chains. The dual supported system had activities at a 107 g/(mol Zr h) level, in the same order of the homogeneous counterpart. Adjusting the Cr/Zr ratio yielded various branching densities and, thus, melting temperatures of the resulting polymers. The samples prepared with the supported 2 exhibited broad differential scanning calorimetry (DSC) curves, probably due to multiple active sites. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie7017564

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