[article]
Titre : |
Isotherms, isosteres, and enthalpy of adsorption of 1,2-dichloroethane from aqueous solution onto activated carbons |
Type de document : |
texte imprimé |
Auteurs : |
Robert Pełech, Auteur |
Année de publication : |
2008 |
Article en page(s) : |
p. 5615-5622 |
Note générale : |
Bibliogr. p. 5622 |
Langues : |
Anglais (eng) |
Mots-clés : |
1,2-dichloroethane -- adsorption Dubinin-Astakhov equation Freundlich |
Résumé : |
In this work the adsorption of 1,2-dichloroethane from aqueous solutions onto DTO, AG5, and WD-ekstra activated carbons has been studied. The adsorption isotherms at the range of temperatures 298-343 K have been described by the Freundlich and Dubinin-Astakhov equations. The characteristic curves of the adsorption process have been determined. It was found out that the temperature dependence of the adsorption equilibrium was described well by the Dubinin-Astakhov model. The isosteric enthalpy of the adsorption was assigned. To describe the dependence of the adsorption isosteric enthalpy on the filling degree, the Do model and the combinations of the van’t Hoff and Dubinin-Astakhov equations in a form of the logarithmic equation were used. |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie0715862 |
in Industrial & engineering chemistry research > Vol. 47 n°15 (Août 2008) . - p. 5615-5622
[article] Isotherms, isosteres, and enthalpy of adsorption of 1,2-dichloroethane from aqueous solution onto activated carbons [texte imprimé] / Robert Pełech, Auteur . - 2008 . - p. 5615-5622. Bibliogr. p. 5622 Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 47 n°15 (Août 2008) . - p. 5615-5622
Mots-clés : |
1,2-dichloroethane -- adsorption Dubinin-Astakhov equation Freundlich |
Résumé : |
In this work the adsorption of 1,2-dichloroethane from aqueous solutions onto DTO, AG5, and WD-ekstra activated carbons has been studied. The adsorption isotherms at the range of temperatures 298-343 K have been described by the Freundlich and Dubinin-Astakhov equations. The characteristic curves of the adsorption process have been determined. It was found out that the temperature dependence of the adsorption equilibrium was described well by the Dubinin-Astakhov model. The isosteric enthalpy of the adsorption was assigned. To describe the dependence of the adsorption isosteric enthalpy on the filling degree, the Do model and the combinations of the van’t Hoff and Dubinin-Astakhov equations in a form of the logarithmic equation were used. |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie0715862 |
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