[article]
Titre : |
Improvement of electrochemical performance of Li[Ni0.8Co0.15Al0.05]O2 cathode materials by AlF3 coating at various temperatures |
Type de document : |
texte imprimé |
Auteurs : |
Byung-Chun Park, Auteur ; Hyung-Bae Kim, Auteur ; Hyun Joo Bang, Auteur ; Jai Prakash, Auteur |
Année de publication : |
2008 |
Article en page(s) : |
p. 3876–3882 |
Note générale : |
Bibliogr. p. 3881-3882 |
Langues : |
Anglais (eng) |
Mots-clés : |
AlF3 coating Electrochemical impedance spectroscopy |
Résumé : |
A thin AlF3 layer of ∼10 nm was uniformly coated on the particle surface of Li[Ni0.8Co0.15Al0.05]O2. The AlF3 coating improved cycle performance at 55, 30, and –10 °C and improved storage characteristics at 60 °C. In studies of differential capacity (dQ/dV) versus voltage, the AlF3-coated Li[Ni0.8Co0.15Al0.05]O2 showed little variation in redox peaks with cycling. Electrochemical impedance spectroscopy suggested that the AlF3 coating played an important role in stabilizing the interface between the cathode and the electrolyte. |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie0715308 |
in Industrial & engineering chemistry research > Vol. 47 n°11 (Juin 2008) . - p. 3876–3882
[article] Improvement of electrochemical performance of Li[Ni0.8Co0.15Al0.05]O2 cathode materials by AlF3 coating at various temperatures [texte imprimé] / Byung-Chun Park, Auteur ; Hyung-Bae Kim, Auteur ; Hyun Joo Bang, Auteur ; Jai Prakash, Auteur . - 2008 . - p. 3876–3882. Bibliogr. p. 3881-3882 Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 47 n°11 (Juin 2008) . - p. 3876–3882
Mots-clés : |
AlF3 coating Electrochemical impedance spectroscopy |
Résumé : |
A thin AlF3 layer of ∼10 nm was uniformly coated on the particle surface of Li[Ni0.8Co0.15Al0.05]O2. The AlF3 coating improved cycle performance at 55, 30, and –10 °C and improved storage characteristics at 60 °C. In studies of differential capacity (dQ/dV) versus voltage, the AlF3-coated Li[Ni0.8Co0.15Al0.05]O2 showed little variation in redox peaks with cycling. Electrochemical impedance spectroscopy suggested that the AlF3 coating played an important role in stabilizing the interface between the cathode and the electrolyte. |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie0715308 |
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