Influence of the competitive adsorbates on the catalytic properties of PtSnNaMg/ZSM-5 catalysts for propane dehydrogenation / Linyang Bai in Industrial & engineering chemistry research, Vol. 50 N° 8 (Avril 2011)
Influence of the competitive adsorbates on the catalytic properties of PtSnNaMg/ZSM-5 catalysts for propane dehydrogenation [texte imprimé] / Linyang Bai, Auteur ; Yuming Zhou, Auteur ; Yiwei Zhang, Auteur . - 2011 . - pp. 4345–4350.
Chimie industrielle
Langues : Anglais (eng)
in Industrial & engineering chemistry research > Vol. 50 N° 8 (Avril 2011) . - pp. 4345–4350
Mots-clés : Catalytic properties Résumé : This paper is aimed at studying the influence of the competitive adsorbates (HCl, lactic acid, and citric acid) on the structural and catalytic properties of PtSnNaMg/ZSM-5 catalysts for propane dehydrogenation. N2 adsorption, X-ray diffraction, inductively coupled plasma, NH3 temperature-programmed desorption, H2 temperature-programmed reduction and transmission electron microscopy were applied for characterization of the prepared catalysts. The catalytic performance was tested in a microreactor. The obtained results indicate that the catalyst prepared in HCl medium exhibited the best catalytic activity and stability due to relatively better metal distribution on the support and/or the strong interactions between Pt and Sn as well as between them and the support. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie1018639