Asymmetric hydrogenation of nonfunctionalized olefins in propylene carbonate — kinetic or thermodynami control? / Sergey P. Verevkin in Industrial & engineering chemistry research, Vol. 51 N° 1 (Janvier 2012)  

Asymmetric hydrogenation of nonfunctionalized olefins in propylene carbonate — kinetic or thermodynami control? [texte imprimé] / Sergey P. Verevkin, Auteur ; Vladimir N. Emel'yanenko, Auteur . - 2012 . - pp. 126-132.
Chimie industrielle
Langues : Anglais (eng)
in Industrial & engineering chemistry research > Vol. 51 N° 1 (Janvier 2012) . - pp. 126-132

Mots-clés :	Kinetics Hydrogenation
Résumé :	Iridium-catalyzed hydrogenations of nonfunctionalized olefins in propylene carbonate as the solvent allow efficient catalysis with much higher enantioselectivities in comparison with dichloromethane which is usually employed for these reactions. Experimental and computational studies of the hydrogenation of 1-methylene-1,2,3,4-tetrahydronaphthalene have been performed to understand the limitation for this reaction.
DEWEY :	660
ISSN :	0888-5885
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