Design and control of a methanol reactor/column process / William L. Luyben in Industrial & engineering chemistry research, Vol. 49 N° 13 (Juillet 2010)
Design and control of a methanol reactor/column process [texte imprimé] / William L. Luyben, Auteur . - 2010 . - pp. 6150–6163.
Chemical engineering
Langues : Anglais (eng)
in Industrial & engineering chemistry research > Vol. 49 N° 13 (Juillet 2010) . - pp. 6150–6163
Mots-clés : Methanol reactor Gas recycle streams Résumé : Methanol is one of the prime candidates for providing an alternative to petroleum-based liquid transportation fuels. It can be made from any renewable biomass hydrocarbon source by partial oxidation in an oxygen-blown gasifier to produce synthesis gas, which is then converted into methanol. The purpose of this paper is to develop the economically optimum design of a methanol reactor/distillation column system with three gas recycle streams to produce high-purity methanol from synthesis gas. The economics consider capital costs, energy costs, the value of the methanol product, and the heating value of a vent stream that is necessary for purging off inert components entering in the feed. A plantwide control structure is developed that is capable of effectively handling large disturbances in the production rate and synthesis gas composition. The unique features of this control scheme are a lack of control of pressure in the reactor/recycle gas loop and a high-pressure override controller to handle stoichiometric imbalances in the composition of the synthesis gas feed. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie100323d